HKU Data Repository

File(s) under permanent embargo

Reason: They are unpublished confidential results.

Supporting data for ''Transition Metal-Catalyzed Functionalization, Anti-Markovnikov Oxidation and Difluorination. And Spectroscopic Characterization of Reactive Iron(IV)-oxo Corrole Intermediate''

posted on 2022-09-26, 08:19 authored by Bin ZhengBin Zheng

File 1 is the supporting data for ''Iron (III)-Porphyrin-Triflate-Catalyzed Anti-Markovnikov Oxidation of Aliphatic Di- and Tri-Substituted Alkenes''. NMR data for substrates and products, as well as X-ray data for Fe-catalyst are included.

File 2 is the supporting data for ''Characterization and Reactivity Study of Fe(IV)-oxo Corrole Cation Radical Species''. NMR, IR, UV, EPR and HR ESI-MS  data for characterization of the reactive Fe-oxo intermediate and mechanistic studies are included.

File 3 is the supporting data for ''Pd-Catalyzed 1,2-Di-fluorination and Di-functionalization of Unactivated Aliphatic Multi-Substituted Alkenes''. NMR data for substrates and products are included.


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