File(s) under embargo
Supporting information for "The Total Synthesis of Pseudolaric Acid B"
File 1 is supporting data for "Construction of the trans-Perhydroazulene Skeleton of Pseudolaric Acids by an Intramolecular CCCC Reaction" Procedure, 1HNMR, 13CNMR, HRMS, IR, [α], optical rotation, and spectrum comparison data for substrates and products, as well as intermediates are included. All spectrum was collected in Department/Laboratory analytical instruments and converted into data (if applicable) in supporting information by known methods. The photos are .png type in vector illustration format for reference.
File 2 is supporting data for "Cleavage of Oxa-Bridge, Installation of Required Methyl Ester, and Construction Tricycle Framework of Pseudolaric Acid B" Procedure, 1HNMR, 13CNMR, HRMS, IR, [α], optical rotation, and spectrum comparison data for substrates and products, as well as intermediates are included. All spectrum was collected in Department/Laboratory analytical instruments and converted into data (if applicable) in supporting information by known methods. The photos are .png type in vector illustration format for reference.
File 3 is supporting data for "Completion of the Total Synthesis of Pseudolaric Acid B". Procedure, 1HNMR, 13CNMR, HRMS, IR, [α], optical rotation, and spectrum comparison data for substrates and products, as well as intermediates are included. All spectrum was collected in Department/Laboratory analytical instruments and converted into data (if applicable) in supporting information by known methods. The photos are .png type in vector illustration format for reference.
Funding
Total synthesis of anti-tumor natural product
National Natural Science Foundation of China
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